The effect of sulfide inclusions on the susceptibility of steels to pitting, stress corrosion cracking and hydrogen embrittlement. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. This article is reporting the sulfide stress cracking of stainless steel 410 in annealed condition. Amine cracking is often intertwined with wet hydrogen sulfide h 2 s and carbonate cracking, as amines, carbonates and wet sulfides often exist together in amine treating systems. Sulfide stress cracking effects high strength effects high strength carbon steels above rockwell hardness 22 especially in petroleum production and petroleum refining. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogenassisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials.
High atomic hydrogen concentrations in carbon steel can lead to sulfide stress cracking ssc of these hard areas. Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. The sulfide stress cracking fracture toughness is primarily a function of alloy composition and microstructure. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Jul 25, 2017 sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. The electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and p110 steel were investigated in a simulated acidic annular environment with lowtemperature and highpressure h2sco2 using electrochemical methods, ubend immersion tests, and scanning electron microscopy. Mechanisms that have been proposed to explain embrittlement include the formation. Ssc is one of the many environmental cracking mechanisms resulting in pipeline steels exposed to aqueous sour service environments. Effect of carbon migration on sulfide stress corrosion.
Bala srinivasan,helmholtzzentrum geesthacht, germanyand v. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels. Field history the production unit is installed as close to the oil wells as possible and is used to separate gas and water from the crude oil. Ssc quickly diminishes performance of downhole tubulars. These tests were carried out on specimens, which were pretreated under the following conditions for 168 hours. Tib and mncrmo was evaluated using constant load tensile test and slow strain rate test in nacetm0177 environment. Bastien and amiot, mechanism of the effect of ionized.
The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. Other mechanisms of introduction of hydrogen into metal are galvanic corrosion, as well as chemical reactions with acids or other chemicals. Another corrosion mechanism that leads to a local cracking of a metal is the hydrogen embrittlement. Test frames for applying cyclic loads with the measurement of crack propagation rates. In this paper, mechanical performance test, slow strain rate test ssrt and optical microscopy analysis were employed in studying the effect of carbon migration on sulfide stress corrosion cracking sscc behaviors of cr5moa3020cr18ni9 dissimilar joints. Anodic and cathodic polarization behaviors of cs also were investigated under the same environmental conditions. Pdf sulfide stress corrosion cracking and hydrogen. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment that comes in contact with sour wet h2s service conditions. Occasionally, both types of cracking are observed in a failure. Environmental cracking results from the conjoint action of three components. Electrochemical and sulfide stress corrosion cracking. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen.
Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. The presence of flaws that concentrate stress or crevices that alter. For example, in those sealing materials in which aerobic microbial respiration. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Is sulfide stress cracking an anodic or a cathodic process. Sulfide stress cracking is the cracking of a metal under the combined action. The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists. Which alloy is for sulfide stress and stress corrosion cracking. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking.
Sscc is a specialized case of hydrogen cracking as it may be possible that sulfide stress corrosion cracking and hydrogen cracking proceed simultaneously. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. The most common forms of wet h 2s cracking are hydrogen induced cracking hic, stressoriented hydrogen induced cracking sohic, and sulfide stress cracking ssc. Failure in pipe gw1 occurred at the weld toe and propagated through the haz figure 4 into the parent material. As a form of hydrogen stress cracking, ssc is a cracking mechanism in pipelines, facilities piping and any equipment.
Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. Biaxial stress corrosion cracking frames capable of conducting testing in aggressive environments, such as brines with co 2 and h 2 s. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. Pdf sulfide stress corrosion cracking and hydrogen induced. Sulfide stress cracking ssc also known as sour gas cracking sour gas. Aug 14, 20 variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. Definition of stress corrosion cracking specific metalenvironment combinations metallurgical aspects of scc electrochemistry of scc scc mechanisms effects. A study on the mechanism of stress corrosion cracking of. The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stress corrosion cracking. Hydrogen sulfide h 2 s is a naturally occurring gas that can be deadly to humans and corrosive to oil and gas equipment, especially in the presence of water. Sulfide stress cracking ssc vs hydrogen induced cracking.
The presence of nonmetallic inclusions enhances susceptibility of steel to hydrogen. Reliability of dissimilar metal welds subjected to sulfide. Tt, on sulfide stress cracking ssc behaviors was estimated mainly via double cantilever beam dcb and electrochemical hydrogen permeation ehp tests. L360nb, j55 and l80 steel grades to stress corrosion and hydrogen induced. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Sulfide stress cracking nace mr01752002, mr0175iso. The hydrogen permeation behavior of carbon steel cs was investigated electrochemically in weak alkaline solutions containing hydrogen sulfide h 2 s with various cyanide ion cn. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. The mechanism of stress relief cracking in the coarsegrained heataffected zone cghaz of a material can be investigated through stress relaxation.
Sulfide stress cracking disambiguation page providing links to topics that could be referred to by the same search term this disambiguation page lists articles associated with the title stress cracking. Sulphide stress cracking is prevented by minimising the hardness and strength of the alloys used for wet h2s systems. Liquid metal cracking lmc, usually a physicochemical process. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Plastic failure through environmental stress cracking. H2s partial pressure, 1 mpa and co2 partial pressure, 1 mpa. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. Copper is known to be susceptible to stress corrosion cracking scc under certain. It is a dangerous type of corrosion which produces some of the toughest technical. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Although the cracking is described as stress cracking, the main problem is the hardness of the parent metal. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Dec 21, 2017 in other words, it can support a stress of 80,000 psi with an elongation of less than 0. Stress corrosion cracking an overview sciencedirect topics.
Processes or conditions involving wet hydrogen sulfide, i. Thorough understanding of scc mechanisms of dss in chloride and hydrogen sulfide containing solutions has been useful for material selection in many. Hydrogen sulfide stress corrosion cracking in materials for. Although the general causes of stress relief cracking are known, different metals or alloys exhibit different types of stress relief mechanisms, but the general underlying mechanisms still unknown. Stress orientated hydrogen induced cracking sohic is a manifestation of sulfide stress cracking ssc in cmn steels by a mechanism involving the linking of planar cracks normal to the primary propagation direction of the crack. Also, atomic hydrogen dissolved in the steel lattice may embrittle areas of hard microstructures in carbon steel base metal or weldments. Laboratory testing of steel l360nb, l80, j55 resistance to sulphide. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure.
Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. One of these chemical reactions involves hydrogen sulfide in sulfide stress cracking ssc, a significant problem for the oil and gas industries. This type of cracking is referred to as stress oriented hydrogen induced cracking sohic. In the solution containing high pressure co2, cr, and p110 steels exhibited general. Sulfide stress cracking ssc testing southwest research. Amine cracking typically occurs on the surface and the cracks are usually radially. Stress corrosion cracking recommended practices canadian. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Hydrogen induced cracking of subsea duplex stainless steel twi.
Sulfide stress cracking of pipelinecase history onepetro. Under acidic gas conditions, the presence of methanol can increase the risk of sulfide stress cracking ssc and stressoriented hydrogen induced cracking. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Following aqueous corrosion reactions in the presence of h2s on the pipe internal surface, atomic hydrogen is produced and absorbed in the pipe steel. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business.
Sulfide stress cracking ssc was first identified and the mechanism outlined in the 1940s after several failures of oil and gas systems in texas and canada. The mechanism of sulfide stress cracking involves a combination of stress corrosion. Because of this, environmental stress cracking and creep rupture are parallel failure mechanisms. Wet h 2 s cracking can occur in susceptible steels exposed to aqueous environments containing hydrogen sulfide. Cracking occurred after less than 12 hours at a strain level of 0. The national association of corrosion engineers nace test method tm0177 is widely used to qualify metals for resistance to sulfide stress cracking and stress corrosion cracking in h 2 s environments. The effect of sulfide inclusions on the susceptibility of. H 2 s can cause sulfide stress cracking of stainless steels. The embrittlement induced by ssc causes failure of steel at a stress level, which is significantly lower than its yield strength. Carbon steels in service in the offshore and oil refinery industries are susceptible to a cracking mechanism known as sulfide stress cracking ssc or hydrogen stress cracking hsc when in sour service, ie when hydrogen sulfide h 2 s is present in the process fluid. Many changes have been made with austenitic stainless steels. Corrosionpedia what is sulfide stress cracking ssc.
In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Susceptibility to sohic for linepipepressure vessel steels twi. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Stress corrosion cracks propagate over a range of velocities from about 103 to 10 mmh, depending upon the combination of alloy and environment involved. Sulfide stress cracking ssc is one of the detrimental types of corrosion which happens in sour environment. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. The understanding of cracking mechanism is complex since there are various factors that can initiate and propagate crack events. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels. Wet hydrogen sulfide h2s cracking inspectioneering. Hydrogen permeation of carbon steel in weak alkaline. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Sulfide stress corrosion cracking of steels corrosion.
Sulfide stress cracking of nickelcontaining lowalloy steels. Therefore, even if cracking were to occur via this mechanism, the crack. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Low alloy steels, stress corrosion cracking, sulfide stress cracking tagged with. It should not be confused with the term stress corrosion cracking which is an anodic. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels, martensitic stainless steels, ferritic stainless steels, austenitic stainless.
Sulfide stress cracking mostly occurs in very highly acidic environments. H2s and hydrogen attackcorrosion refining, hydrocarbons. The list of acronyms and abbreviations related to ssc sulfide stress cracking. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. Sulfide stress cracking nicontaining steels transformation start temperature, i. Localized corrosion is one of the most pervasive forms of attack impacting virtually all engineering metals and alloys that derive their resistance.
Standard material requirements sulfide stress cracking. Sulfide stress cracking ssc is just one of several forms of hydrogen. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Reliability of dissimilar metal welds subjected to sulfide stress cracking vol. Amine cracking is a form of stress corrosion cracking, which is related to alkaline and carbonate stress corrosion cracking. Sulfide stress cracking ssc cracking usually is designated as either intergranular intercrystalline or transgranular transcrystalline. Materials free fulltext sulfide stress cracking behavior of a. Specialized stress corrosion cracking testing capabilities.
Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Sour cracking hic, sulfide stress corrosion cracking sscc environmentally assisted cracking can also occur internally in pipelines. Rosen 15 types of pipeline cracks inspection solutions. It is a form of hydrogenrelated cracking and can have two distinct morphologies. An industry value that has been developed is nace mr01. Apart from sscc, h2s also cause other cracking, including stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stress oriented hydrogen induced cracking, soft zone cracking and galvanically induced hydrogen stress cracking. Methanol can increase the rate of vapor phase corrosion, which directly increases the risk of a topoftheline corrosion failure. Ian sutton, in plant design and operations second edition, 2017. Partial pressure of the h 2 s is determined by multiplying the mole fraction of h 2 s in the gas by the total pressure. Sulfide stress cracking oil and gas pipelines wiley. The variation of the name is due to the lack of agreement in the mechanism of failure. Their geometry is such that if they grow to appropriate lengths they may reach a critical size that results in a transition from the relatively slow crack. Sulfide stress cracking nace mr01752002, mr0175iso 15156.
Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. The most common conditions for these are sour environments. Stress corrosion cracking is the cracking of a susceptible metal under the mixed influence of a tensile stress either residual or applied in a corrosive environment 46. Fundamentals of stress corrosion cracking researchgate. Element performs sulfide stress cracking ssc testing of metals subject to cracking under the combined action of tensile stress and corrosion in the presence of water and h2s, in compliance with nace tm0177 iso 15156 standards. Sulfide stress cracking an overview sciencedirect topics. The use of dss has been restricted in some cases because of stress corrosion cracking scc, which can initiate and grow in either the ferrite or austenite phase depending on the environment. Sulfide stress cracking of stainless steel 410 in sour crude. Factors affecting the sulfide stress cracking performance. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel.
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